Conversion of Phosphinic into Phosphinous Esters through Nickelocene Reduktion-complexation of Phosphinothioic O-Esters. A New Synthesis of Carbon-phosphorus Heterocycles

DOI: 10.1039/c39800000191

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Journal of the Chemical Society. Chemical communications p. 191 - 192 (1980)

Update date:2022-08-05

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Authors:

Mathey, Francois

Mercier, Francois

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Article abstract of DOI:10.1039/c39800000191

A new procedure for reducing a phosphinate (LO) into the corresponding phosphinite (L) includes the following steps: LO -> LS -> CpNi(I)L -> NiL4 -> L (Cp = cyclopentadiene); such as scheme is illustrated by the syntheses of 2-phenyl-1,2-oxaphospholane an

Full text of DOI:10.1039/c39800000191

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