Tetrahedron Letters p. 1119 - 1122 (1984)
Update date:2022-08-05
Topics:
Cane, David E.
Whittle, Yvonne G.
Liang, Tzyy-Chyau
Feedings of <1-13C>- and <1,2-13C2>acetate to Aspergillus terreus gave quadrone and terrecyclic acid which were analyzed by 13C NMR.The pattern of 13C-enrichments and couplings is consistent with the formation of 1 and 2 by cyclization of farnesyl pyrophosphate.
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