Chemical Communications p. 1437 - 1438 (1996)
Update date:2022-09-26
Topics:
Liu, Mao-Huang
Yeh, Chen-Yu
Su, Y. Oliver
A stable high-valent oxoferryl porphyrin radical cation is electrochemically generated in aqueous media at room temperature which rapidly catalyses the oxidation of alkenes to give eneones and diols; by contrast the oxoferryl porphyrin only slowly catalyses oxidation and gives only the eneone.
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