Methylaluminum bis(4-substituted-2,6-di-tert-butylphenoxide) as an efficient nonchelating Lewis acid: Application to asymmetric Diels-Alder reaction and diastereoselective alkylation to alkoxy carbonyl substrates

DOI: 10.1016/S0040-4020(01)85366-7

Source and publish data:

Tetrahedron p. 8983 - 8996 (1994)

Update date:2022-09-26

Topics:

Authors:

Maruoka, Keiji

Oishi, Masataka

Shiohara, Kei

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4020(01)85366-7

The exceptionally bulky methylaluminum bis(4-substituted-2,6-di-tert-butylphenoxide) such as MAD or MABR can be successfully utilized as a highly efficient nonchelating Lewis acid for achieving high stereoselectivity in 1,n asymmetric induction in cyclic

Full text of DOI:10.1016/S0040-4020(01)85366-7

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