Ene-Type Reaction through the Intermediacy of the 1,4-Dipolar Ion in the Reaction of Tetracyanoethylene with Nucleophilic Double Bonds in Liquid Sulfur Dioxide

DOI: 10.1021/jo01311a010

Source and publish data:

Journal of Organic Chemistry p. 4602 - 4605 (1980)

Update date:2022-08-05

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Authors:

Masilamani, Divakar

Reuman, Michael E.

Rogic, Milorad M.

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Article abstract of DOI:10.1021/jo01311a010

The expected <2 + 2> cycloadduct from the reaction of tetracyanoethylene with 1-methoxycyclohexene in liquid sulfur dioxide underwent a previously unrecognized reaction to give 1-methoxy-6-(1,1,2,2-tetracyanoethyl)-cyclohexene.Further isomerization of thi

Full text of DOI:10.1021/jo01311a010

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