?-Facial Stereoselectivity: Rates and Stereoselectivities of Cycloadditions of Hexachlorocyclopentadiene to 7-Substituted Norbornadienes, and Photoelectron Spectral and Molecular Orbital Computational Investigations of Norbornadienes

DOI: 10.1021/ja00541a017

Source and publish data:

Journal of the American Chemical Society p. 6482 - 6490 (1980)

Update date:2022-08-05

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Authors:

Mazzocchi, Paul H.

Stahly, Barbara

Dodd, John

Rondan, Nelson G.

Domelsmith, L.N.

et al. et al.

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Article abstract of DOI:10.1021/ja00541a017

The partial rate factors for the Diels-Alder cycloadditions of hexachlorocyclopentadiene to 7-substituted norbornadienes in the four possible modes were measured.Syn-endo and anti-endo rates are essentially identical and decrease slightly as the effective

Full text of DOI:10.1021/ja00541a017

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