DIAZADIEN-NICKEL-ALKYLE

DOI: 10.1016/S0022-328X(00)88576-9

Source and publish data:

Journal of Organometallic Chemistry p. 321 - 328 (1980)

Update date:2022-08-03

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Authors:

Svoboda, Michael

Dieck, Heindirk tom

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Article abstract of DOI:10.1016/S0022-328X(00)88576-9

Low temperature reactions of diazadienes (DAD), R'N=C(R)C(R)=NR', and nickel halides or complexes (DAD)NiX2 with CH3MgI yield deep green solutions of (DAD)Ni(CH3)2 which decompose readily on warming except in cases of 2,6-disubstituted N-aryl groups R'.Th

Full text of DOI:10.1016/S0022-328X(00)88576-9

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