Tetrahedron p. 4573 - 4582 (1999)
Update date:2022-09-26
Topics:
Mori, Atsunori
Fujita, Akinori
Kajiro, Hiroshi
Nishihara, Yasushi
Hiyama, Tamejiro
Reduction of several α,β-unsaturated ketones with dimethylphenylsilane and 10-100 mol% of CuF(PPh3)3 · 2EtOH or CuCl/PPh3/Bu4NF proceeds in a 1,4-selective manner to give the corresponding saturated ketones in up to >99% yield.
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