Radical-Nucleophilic Substitution (SRN1) Reactions. Part 2. Preparation and Reactions of α-Nitrosulphides

DOI: 10.1039/P19840002327

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2327 - 2336 (1984)

Update date:2022-08-04

Topics:

Authors:

Bowman, W. Russell

Rakshit, Devajvoti

Valmas, Michael D.

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Article abstract of DOI:10.1039/P19840002327

A range of α-nitrosulphides have been prepared by oxidative addition of thiolate anion to the anion of 2-nitropropane, S_N2 attack of the anion of 2-nitropropane on symmetrical disulphides, and S_RN1 reaction of 2-substituted-2-nitropropanes with thiolate anions.The α-nitrosulphides undergo S_RN1 substitution with the anion of 2-nitropropane, and S_RN1 substitution or redox reactions with thiolate anions.The electron spin resonance (e.s.r.) spectrum of the radical-anion of 1-methyl-1-nitroethyl pyrimidin-2-yl sulphide has been observed.

Full text of DOI:10.1039/P19840002327

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