
Journal of Organic Chemistry p. 316 - 320 (1981)
Update date:2022-08-04
Topics: Thermolysis in situ Furoxan
Brittelli, David R.
Boswell, George A.
Diacylfuroxans yield two types of nitrile oxides in situ when heated in solution.Uncrowded diacylfuroxans rearrange to α-acyloximino nitrile oxides; diacylfuroxans with bulky substituents give rise to the "half-molecule" acyl nitrile oxides.Intermediate c
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