Photochemical Reactivity of Keto Amidines. Type I Rearrangement to Aminocyclopropyl Isocyanates and Photochemical Generation of Bisisocyanates from Bichromophoric Systems

DOI: 10.1021/jo00319a008

Source and publish data:

Journal of Organic Chemistry p. 1082 - 1086 (1981)

Update date:2022-07-29

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Authors:

Swanson, Barry J.

Crockett, Geoffrey C.

Koch, Tad H.

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Article abstract of DOI:10.1021/jo00319a008

The photocemical rearrangement of 2-aminopyrrolin-5-ones and bis(2-aminopyrrolin-5-ones) toaminocyclopropyl isocyanates and bis(aminocyclopropylisocyanates) is described.Specifically, 2-(dimetylamino)pyrrolin-5-one(3), 2-(methylphenylamino)pyrrolin-5-one

Full text of DOI:10.1021/jo00319a008

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