Tetrahedron p. 1399 - 1408 (1980)
Update date:2022-08-05
Topics:
Clive, Derrick L.J.
Russell, Charles G.
Chittattu, Gim
Singh, Alok
Experimental procedures are described for the synthetically useful reaction by which olefinic acids are converted into lactones carrying a benzeneseleno-group. Data are presented to define some of the mechanistic details of this type of cyclofunctionalisation and kinetic and thermodynamic factors relevant to the Rules for Ring Closure are discussed. A nomenclature is introduced for a treatment of ring-fusion stereochemistry.
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