Bulletin of the Chemical Society of Japan p. 3464 - 3470 (1983)
Update date:2022-08-04
Topics:
Sawaki
The photooxidation of phenanthrenequinone (PhQ) under oxygen afforded diphenic acid and its peroxy acid, while acenaphthenequinone (AcQ) predominantly yielded 1,8-naphthalenedicarboxylic anhydride. The photolysis of PhQ or AcQ in the presence of olefins afforded predominantly 1:1 cycloadducts and the photoepoxidation was a very minor one accompanying significant amount of C-C clevage of olefins. These results show that the photoreaction of PhQ or AcQ with olefins is very fast and competitive with the quenching and/or reaction with oxygen. The photoepoxidation of stilbene in the presence of dimethyl sulfoxide resulted in a high selectivity ( greater than 98%) for the trans-epoxide.
View MoreJiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd
Contact:+86-517-86283327
Address:9 North Hantai Road, Huaian, China
Contact:+86-134-5286-9121
Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Contact:+65 9658 0999
Address:26 Sin Ming Lane, Midview City, #05-118, Singapore 573971
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Contact:021-50278900
Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
Doi:10.1016/S0040-4039(00)71489-4
(1980)Doi:10.1021/jo01279a025
(1967)Doi:10.1134/S1070427214120167
(2014)Doi:10.1016/0040-4020(94)01081-A
(1995)Doi:10.1016/S0040-4039(00)78755-7
(1980)Doi:10.1021/ja00390a036
(1982)
