
Bulletin of the Chemical Society of Japan p. 3464 - 3470 (1983)
Update date:2022-08-04
Topics:
Sawaki
The photooxidation of phenanthrenequinone (PhQ) under oxygen afforded diphenic acid and its peroxy acid, while acenaphthenequinone (AcQ) predominantly yielded 1,8-naphthalenedicarboxylic anhydride. The photolysis of PhQ or AcQ in the presence of olefins afforded predominantly 1:1 cycloadducts and the photoepoxidation was a very minor one accompanying significant amount of C-C clevage of olefins. These results show that the photoreaction of PhQ or AcQ with olefins is very fast and competitive with the quenching and/or reaction with oxygen. The photoepoxidation of stilbene in the presence of dimethyl sulfoxide resulted in a high selectivity ( greater than 98%) for the trans-epoxide.
View MoreContact:0571-
Address:zhejing
Xi'an yuanfar international trade company
website:https://www.yuanfarchemical.com
Contact:86-029-88745613 ext 828
Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
Contact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
Daqing E-shine Chemical Co.,LTD
Contact:0086-024-31285112
Address:Hongweiyuan area, Ranghulu district
Dayang Chem (Hangzhou) Co.,Ltd.
website:http://www.dycnchem.com
Contact:+86-571-88938639
Address:9/F, Unit 2 Changdi Torch Building, 259# WenSan Road, Xihu District, Hangzhou City 310012, P.R.China
Doi:10.1016/S0040-4039(00)71489-4
(1980)Doi:10.1021/jo01279a025
(1967)Doi:10.1134/S1070427214120167
(2014)Doi:10.1016/0040-4020(94)01081-A
(1995)Doi:10.1016/S0040-4039(00)78755-7
(1980)Doi:10.1021/ja00390a036
(1982)