Bulletin of the Chemical Society of Japan p. 3464 - 3470 (1983)
Update date:2022-08-04
Topics:
Sawaki
The photooxidation of phenanthrenequinone (PhQ) under oxygen afforded diphenic acid and its peroxy acid, while acenaphthenequinone (AcQ) predominantly yielded 1,8-naphthalenedicarboxylic anhydride. The photolysis of PhQ or AcQ in the presence of olefins afforded predominantly 1:1 cycloadducts and the photoepoxidation was a very minor one accompanying significant amount of C-C clevage of olefins. These results show that the photoreaction of PhQ or AcQ with olefins is very fast and competitive with the quenching and/or reaction with oxygen. The photoepoxidation of stilbene in the presence of dimethyl sulfoxide resulted in a high selectivity ( greater than 98%) for the trans-epoxide.
View MoreContact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Chongqing Shuangfeng Chemical Co.,Ltd
Contact:+86-23-49850156
Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Zouping Fuhai Technology Development Co., Ltd.
Contact:+0532-86934525 18660293207
Address:jiuhu town industrial park Zouping County,bingzhou Provincejiuhu town industrial park
SHANGHAI SYSTEAM BIOCHEM CO., LTD
website:http://www.systeambc.com
Contact:86-021-58380978
Address:Building 87，Lane 669， Dong Jing Road Shanghai,P.R.China
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD
Contact:+86-576-88685096
Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
Doi:10.1016/S0040-4039(00)71489-4
(1980)Doi:10.1021/jo01279a025
(1967)Doi:10.1134/S1070427214120167
(2014)Doi:10.1016/0040-4020(94)01081-A
(1995)Doi:10.1016/S0040-4039(00)78755-7
(1980)Doi:10.1021/ja00390a036
(1982)
