Base Catalysed Rearrangements involving Ylide Intermediates. Part 2. The Stevens and Sigmatropyc Rearrangements of Allylic Ammonium Ylides

DOI: 10.1039/P19800001450

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1450 - 1457 (1980)

Update date:2022-07-30

Topics: Intermediates Rearrangements Ylide Base catalysed

Authors:

Jemison, Robert W.

Laird, Trevor

Ollis, W. David

Sutherland, Ian O.

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Article abstract of DOI:10.1039/P19800001450

The base catalysed rearrangements of the quaternary ammonium salts (9) usually gives the <3,2> sigmatropic rearrangement product (10) rather than the Stevens <1,2> rearrangement product (11).An earlier claim has been corrected: the corresponding reaction

Full text of DOI:10.1039/P19800001450

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