Nitrile Sulphide Formation from the Thermal Fragmentation of 1,3,4-Oxathiazoles: a Retro-1,3-dipolar Cycloaddition

DOI: 10.1039/c39800000714

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 714 - 715 (1980)

Update date:2022-08-03

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Authors:

Paton, R. Michael

Robertson, Fiona M.

Ross, John F.

Crosby, John

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Article abstract of DOI:10.1039/c39800000714

1,3,4-Oxathiazoles, on thermolysis, undergo retro-1,3-dipolar cycloaddition to afford carbonyl compounds and nitrile sulphides, which may be trapped by cycloaddition with alkynes and nitriles.

Full text of DOI:10.1039/c39800000714

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