Coupling Reactions of Vinylmagnesium Bromide with Imidoyl Chlorides and with Amides. Synthesis of Enol Imines, γ,δ-Unsaturated Ketones, and Ketimines

DOI: 10.1021/jo00318a045

Source and publish data:

Journal of Organic Chemistry p. 1039 - 1041 (1981)

Update date:2022-08-05

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Authors:

Ng, Kai S.

Alper, Howard

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Article abstract of DOI:10.1021/jo00318a045

Vinylmagnesium bromide undergoes successive addition to imidoyl chlorides and to amides to give unsaturated ketones, imines, enol imines, or enamines, depending on the reaction conditions.

Full text of DOI:10.1021/jo00318a045

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Article Doi

Coupling Reactions of Vinylmagnesium Bromide with Imidoyl Chlorides and with Amides. Synthesis of Enol Imines, γ,δ-Unsaturated Ketones, and Ketimines

DOI: 10.1021/jo00318a045

Source and publish data:

Authors:

Article abstract of DOI:10.1021/jo00318a045

Full text of DOI:10.1021/jo00318a045

Products guided by the article

R&D Labs maybe for 76173-13-2

Relevant to this article

An Efficient and General Synthesis of 5-Substituted Pyrrolidinones

Alkylation and Subsequent Decomposition of Arenesulfonylhydrazone Dianions

Dihydromyrcenol carbonylation catalyzed by palladium-tin precursors: Selectivity of the reaction drawn by the experimental conditions and the co-reactants

Synthetic approach toward antibiotic tunicamycins - VI. Total synthesis of tunicamycins

Synthesis and solution and solid-state studies of cobaloxime complexes containing alkylated 6-aminopurine ligands. Molecular and crystal structure of the complex with N(7)-bound 3-benzyladenine and dimethyl phosphonate as the axial ligands