Coupling Reactions of Vinylmagnesium Bromide with Imidoyl Chlorides and with Amides. Synthesis of Enol Imines, γ,δ-Unsaturated Ketones, and Ketimines

DOI: 10.1021/jo00318a045

Source and publish data:

Journal of Organic Chemistry p. 1039 - 1041 (1981)

Update date:2022-08-05

Topics:

Authors:

Ng, Kai S.

Alper, Howard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00318a045

Vinylmagnesium bromide undergoes successive addition to imidoyl chlorides and to amides to give unsaturated ketones, imines, enol imines, or enamines, depending on the reaction conditions.

Full text of DOI:10.1021/jo00318a045

Products guided by the article

Product name:(4-Chloro-phenyl)-methyl-((E)-1-phenyl-penta-1,4-dienyl)-amine

Cas No:76173-13-2

R&D Labs maybe for 76173-13-2

SPRING CHEMICAL INDUSTRY CO.,LTD

Contact:86-187-66672125

Address:linchi industry park.zouping
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China
Shanghai agrotree chemical co.,ltd.

Contact:+86-21-50117563

Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Hebei DaPeng Pharm & Chem Co., Ltd.

Contact:86-317-7298678,0576-88861898 88861908

Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China

Relevant to this article

An Efficient and General Synthesis of 5-Substituted Pyrrolidinones

Doi:10.1021/jo00321a017
(1981)
Doi:10.1021/jo01279a007
(1967)
Alkylation and Subsequent Decomposition of Arenesulfonylhydrazone Dianions

Doi:10.1021/jo00320a016
(1981)
Dihydromyrcenol carbonylation catalyzed by palladium-tin precursors: Selectivity of the reaction drawn by the experimental conditions and the co-reactants

Doi:10.1016/S0022-328X(01)01245-1
(2002)
Synthetic approach toward antibiotic tunicamycins - VI. Total synthesis of tunicamycins

Doi:10.1016/S0040-4039(01)81486-6
(1984)
Synthesis and solution and solid-state studies of cobaloxime complexes containing alkylated 6-aminopurine ligands. Molecular and crystal structure of the complex with N(7)-bound 3-benzyladenine and dimethyl phosphonate as the axial ligands

Doi:10.1021/ic50219a036
(1981)

Article Doi