
Journal of the Chemical Society. Chemical communications p. 758 - 759 (1980)
Update date:2022-08-04
Topics:
Fujii, Tozo
Saito, Tohru
Nakasaka, Tsuyoshi
Methylation of N'-benzyloxy-1-(2-deoxy-β-D-ribofuranosyl)-5-formamidoimidazole-4-carboxamidine (2a) followed by hydrogenolysis of the N'-benzyloxy-group and cyclization produced the hitherto unknown 3-methyl-2'-deoxyadenosine (5a), which was readily hydrolysed to 3-methyladenine (6) in H2O at pH =7.0 and to (6) and the imidazole-(2-deoxy)riboside (4a) at pH 8.98.
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