Rearrangement of α-Acetylenic Alcohols Substituted with Δ1-Pyrroline

DOI: 10.1002/ardp.19803131008

Source and publish data:

Archiv der Pharmazie p. 858 - 867 (1980)

Update date:2022-08-02

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Authors:

Dannhardt, Gerd

Obergrusberger, Richard

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Article abstract of DOI:10.1002/ardp.19803131008

α-Acetylenic alcohols substituted with Δ¹-pyrroline are formed by 1,2-addition of 2-alkyl-Δ¹-pyrrolines to propargylic aldehydes.Thermolytic rearrangement of the products leads to vinylogous formamides and Meyer-Schuster products.

Full text of DOI:10.1002/ardp.19803131008

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