Rearrangement of α-Acetylenic Alcohols Substituted with Δ1-Pyrroline

DOI: 10.1002/ardp.19803131008

Source and publish data:

Archiv der Pharmazie p. 858 - 867 (1980)

Update date:2022-08-02

Topics:

Authors:

Dannhardt, Gerd

Obergrusberger, Richard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/ardp.19803131008

α-Acetylenic alcohols substituted with Δ¹-pyrroline are formed by 1,2-addition of 2-alkyl-Δ¹-pyrrolines to propargylic aldehydes.Thermolytic rearrangement of the products leads to vinylogous formamides and Meyer-Schuster products.

Full text of DOI:10.1002/ardp.19803131008

Products guided by the article

Product name:4-Methyl-4-(Δ1'-pyrrolin-2'-yl)-2-penten-1-al

Cas No:76238-09-0

R&D Labs maybe for 76238-09-0

Nanjing Fubang Chemical Co.,Ltd

Contact:+86-25-83179199

Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China
Guarson Chemical Co., Ltd.

website:http://www.guarson.com

Contact:+86-523-88059600,+86-13805268803

Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China

Relevant to this article

Latrunculins: NMR study, two new toxins and a synthetic approach

Doi:10.1016/S0040-4020(01)96553-6
(1985)
Synthesis of the Hexasaccharide Fragment of Landomycin A Using a Mild, Reagent-Controlled Approach

Doi:10.1021/acs.orglett.9b01118
(2019)
Oxotungsten(IV)-acetylene complexes: Synthesis via intermetal oxygen atom transfer and nuclear magnetic resonance studies

Doi:10.1021/ic50218a056
(1981)
Heterocycles with a bridgehead nitrogen atom. 16. Assembly of a peri-fused system from an angular tricycle by recyclization of an oxazole ring into pyrrole one

Doi:10.1007/s11172-005-0248-x
(2005)
Restricted Rotation in Pentaarylpyrroles

Doi:10.1021/jo00320a056
(1981)
Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts

Doi:10.1246/cl.190679
(2019)

Article Doi