Rearrangement of α-Acetylenic Alcohols Substituted with Δ1-Pyrroline

DOI: 10.1002/ardp.19803131008

Source and publish data:

Archiv der Pharmazie p. 858 - 867 (1980)

Update date:2022-08-02

Topics:

Authors:

Dannhardt, Gerd

Obergrusberger, Richard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/ardp.19803131008

α-Acetylenic alcohols substituted with Δ¹-pyrroline are formed by 1,2-addition of 2-alkyl-Δ¹-pyrrolines to propargylic aldehydes.Thermolytic rearrangement of the products leads to vinylogous formamides and Meyer-Schuster products.

Full text of DOI:10.1002/ardp.19803131008

Products guided by the article

Product name:4-Methyl-4-(Δ1'-pyrrolin-2'-yl)-2-penten-1-al

Cas No:76238-09-0

R&D Labs maybe for 76238-09-0

uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Henan Harvest Chem Co., Ltd

Contact:+86-371-86058576

Address:NO.32, Jingsan Road, Zhengzhou, China
shanghai hekang chemical co.ltd

Contact:021-54173790

Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Yangzhou Zhongbao Pharmaceutical Co.,Ltd

Contact:+86-514-88290838

Address:Jiangsu Baoying county economic develpment zone in baoying avenue91

Relevant to this article

Latrunculins: NMR study, two new toxins and a synthetic approach

Doi:10.1016/S0040-4020(01)96553-6
(1985)
Synthesis of the Hexasaccharide Fragment of Landomycin A Using a Mild, Reagent-Controlled Approach

Doi:10.1021/acs.orglett.9b01118
(2019)
Oxotungsten(IV)-acetylene complexes: Synthesis via intermetal oxygen atom transfer and nuclear magnetic resonance studies

Doi:10.1021/ic50218a056
(1981)
Heterocycles with a bridgehead nitrogen atom. 16. Assembly of a peri-fused system from an angular tricycle by recyclization of an oxazole ring into pyrrole one

Doi:10.1007/s11172-005-0248-x
(2005)
Restricted Rotation in Pentaarylpyrroles

Doi:10.1021/jo00320a056
(1981)
Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts

Doi:10.1246/cl.190679
(2019)

Article Doi