Tetrahedron p. 557 - 561 (1982)
Update date:2022-08-05
Topics:
Babudri, F.
Ciminale, F.
Nunno, L. Di
Florio, S.
N,N-Disubstituted carboxamides containing α-hydrogen atoms undergo self-condensation reaction simply on treatment with Grignard reagents or n-BuLi in THF at room temp.The reaction is considerably influenced by steric hindrance at the α-carbon and the condensing agent utilized.A possible Claisen-type mechanism is also reported.
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(1953)
