Highly diastereoselective and enantioselective C-H functionalization of 1,2-dihydronaphthalenes: A combined C-H activation/cope rearrangement followed by a retro-cope rearrangement

DOI: 10.1021/ja047185k

Source and publish data:

Journal of the American Chemical Society p. 10862 - 10863 (2004)

Update date:2022-09-26

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Authors:

Davies, Huw M. L.

Jin, Qihui

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Article abstract of DOI:10.1021/ja047185k

The Rh₂(S-DOSP)₄-catalyzed reaction of vinyldiazoacetates with dihydronaphthalenes results in a highly enantioselective (91-99.6% ee) and diastereoselective (>98% de) C-H functionalization. The apparent intermolecular C-H insertion w

Full text of DOI:10.1021/ja047185k

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