C-acylation of enolates from lithium dimethylcuprate addition to α,β-unsaturated ketones

DOI: 10.1016/S0040-4039(00)92600-5

Source and publish data:

Tetrahedron Letters p. 2337 - 2340 (1980)

Update date:2022-08-04

Topics:

Authors:

Bernasconi

Gariboldi

Jommi Jommi

Sisti Sisti

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92600-5

The enolates from 1,4 addition of lithium dimethylcuprate to 2-cyclohexenone, 2-cyclopentenone and methyl vinyl ketone, with acetyl chloride, give only C-acylated products and not O-acylated products as previously reported in literature.

Full text of DOI:10.1016/S0040-4039(00)92600-5

Products guided by the article

Product name:1-acetoxy-2-acetyl-3-methylcyclohexene

Cas No:76638-59-0

R&D Labs maybe for 76638-59-0

Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
LIAOYANG TENGYUAN FOOD ADDITIVE FACTORY

Contact:+86-419-5807666

Address:Haodianzi village,Hanling Town,Liaoyang county
HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong

Relevant to this article

Synthesis and structures of 1,2-bis(imino)acenaphthene (BIAN) lanthanide complexes that involve the transfer of zero, one, or two electrons

Doi:10.1039/b708758f
(2007)
Crystal Structures and Phase Sequences of Metallocenium Salts with Fluorinated Anions: Effects of Molecular Size and Symmetry on Phase Transitions to Ionic Plastic Crystals

Doi:10.1002/chem.201603170
(2016)
Solid-phase synthesis of hydrazinopeptides in Boc and Fmoc strategies monitored by HR-MAS NMR

Doi:10.1016/j.tet.2007.07.038
(2007)
A supramolecular optic sensor for selective recognition AMP

Doi:10.1016/j.inoche.2010.04.006
(2010)
A practical formal synthesis of camptothecin

Doi:10.1016/j.tetlet.2007.07.017
(2007)
DIRECT CONVERSION OF D-GLUCOSAMINE INTO D-GULOSAMINE

Doi:10.1016/S0008-6215(00)90783-3
(1984)

Article Doi