C-acylation of enolates from lithium dimethylcuprate addition to α,β-unsaturated ketones

DOI: 10.1016/S0040-4039(00)92600-5

Source and publish data:

Tetrahedron Letters p. 2337 - 2340 (1980)

Update date:2022-08-04

Topics:

Authors:

Bernasconi

Gariboldi

Jommi Jommi

Sisti Sisti

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Article abstract of DOI:10.1016/S0040-4039(00)92600-5

The enolates from 1,4 addition of lithium dimethylcuprate to 2-cyclohexenone, 2-cyclopentenone and methyl vinyl ketone, with acetyl chloride, give only C-acylated products and not O-acylated products as previously reported in literature.

Full text of DOI:10.1016/S0040-4039(00)92600-5

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