Electron Transfer in the Reactions of Geminal Dihalides with Ph2P(-). Evidence for the Formation of a Carbene Intermediate from a Radical Precursor

DOI: 10.1021/jo00127a014

Source and publish data:

Journal of Organic Chemistry p. 7117 - 7124 (1995)

Update date:2022-07-30

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Authors:

Ashby, E. C.

Deshpande, Abhay K.

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Article abstract of DOI:10.1021/jo00127a014

The reactions of two sterically hindered geminal dihalides, 6,6-dichloro-5,5-dimethyl-1-hexene (5a) and 6,6-diiodo-5,5-dimethyl-1-hexene (5b), with Ph2P(-) have been found to involve a single electron transfer (SET) pathway.Since the corresponding monochl

Full text of DOI:10.1021/jo00127a014

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