Tetrahedron p. 2305 - 2310 (1980)
Update date:2022-08-04
Topics:
Chuit, C.
Foulon, J. P.
Normant, J. F.
Nearly exclusive 1-4 addition products are obtained by action of lithium dialkylcuprates with α,β-ethylenic aldehydes.Non polar solvents and low temperatures favor this reaction.Only α,β-ethylenic aldehydes having a trisubstituted double bond give a relatively important proportion of 1-2 addition product.
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