Journal of the Chemical Society. Perkin transactions I p. 457 - 461 (1981)
Update date:2022-08-05
Topics:
Bulman-Page, Philip C.
Ley, Steven V.
Morton, Judith A.
Williams, David J.
Sulphuryl chloride reacts with 1,3-oxathiolans and 1,3-dithiolans to afford unstable intermediate trans-2,3-dichloro-1,4-oxathians or trans-2,3-dichloro-1,4-dithians.Some of these intermediates can be converted on hydrolytic work up to α-ketothioacetals in reasonable yield.Intermediates in the rearrangement pathway have been identified.Reaction of 6-oxospiro
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(1980)Doi:10.1016/0040-4020(80)80221-3
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(1981)Doi:10.1016/S0957-4166(98)00275-4
(1998)Doi:10.1007/s11137-005-0079-5
(2005)
