USE OF 2,4,6-TRI-ISOPROPYLBENZENESULPHONYL HYDRAZIDE IN THE McFADYEN-STEVENS ALDEHYDE SYNTHESIS

DOI: 10.1016/0040-4039(80)80096-7

Source and publish data:

Tetrahedron Letters p. 4645 - 4648 (1980)

Update date:2022-09-26

Topics:

Authors:

Dudman, Christopher C.

Grice, Peter

Reese, Colin B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(80)80096-7

Aroyl derivatives of 2,4,6-tri-isopropylbenzenesulphonyl hydrazide decompose readily in the presence of potassium carbonate in boiling methanol solution to give aldehydes and varying quantities of the corresponding alcohols and methyl esters.The formation of the latter by-products is supressed and good yields of aldehydes are obtained when hydrazine is added to the reaction medium.

Full text of DOI:10.1016/0040-4039(80)80096-7

Products guided by the article

Product name:Benzoic acid, 2-methyl-, 2-[[2,4,6-tris(1-methylethyl)phenyl]sulfonyl]hydrazide

Cas No:77229-17-5

R&D Labs maybe for 77229-17-5

Shandong Xinhua Pharmaceutical Co.,Ltd

website:http://www.xhzy.com

Contact:+86-533-2196801

Address:1 lutai road,zhangdian dis,Zibo City
Hangzhou Pharma & Chem Co.,Ltd.

Contact:+86-571-87040515

Address:No,139Qingchun Rd
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Shanghai He Yang International Trading Co., Ltd.

Contact:+86-21-52043598

Address:Room 816, Blag.5, No.58 Huachi Road
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town

Relevant to this article

Preparation of the Ru3(CO)8-pyridine-alcohol cluster and its use for the selective catalytic transformation of primary to secondary amines

Doi:10.1039/c8dt02972e
(2018)
Discovery of L-791,943: a potent, selective, non emetic and orally active phosphodiesterase-4 inhibitor.

Doi:10.1016/S0960-894X(02)00190-7
(2002)
Novel reactions of metal-metal bonds. Reactions of Pd₂{(C₆H₅)₂PCH₂P(C ₆H₅)₂}₂Cl₂ with acetylenes, olefins, and isothiocyanates

Doi:10.1021/ic50222a026
(1981)
STEREOCHEMICAL STUDIES-75 SATURATED HETEROCYCLES-62. CONNECTION BETWEEN THE DIASTEREOSELECTIVITY AND THE DOMINANT CONFORMATION IN THE FORMATION OF CONDENSED-SKELETON 1,3-OXAZINES, FIRST X-RAY DIFFRACTION EVIDENCE OF N-OUTSIDE CONFORMATION

Doi:10.1016/S0040-4020(01)91511-X
(1984)
KINETIC OF NUCLEOPHILIC ATTACK ON COORDINATED ORGANIC MOIETIES. XIV. THE SIGNIFICANCE OF AMINE BASICITY IN DETERMINING THE NUCLEOPHILICITIES OF PYRIDINES AND ANILINES TOWARDS <(1-5-η-Dienyl)(Fe(CO)3>⁺ CATIONS

Doi:10.1016/S0022-328X(00)83705-5
(1980)
Doi:10.1021/ja01148a529
(1951)

Article Doi