Sulphur-substituted Organotin Compounds. Part 8. Preparation and Reactions of 3-(p-Tolylthio)propyl- and 4-(p-Tolylthio)butyl-triphenyltin. Interactions with Tetracyanoethylene

DOI: 10.1039/DT9820002321

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2321 - 2326 (1982)

Update date:2022-08-04

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Authors:

Wardell, James L.

Wigzell, John McM.

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Article abstract of DOI:10.1039/DT9820002321

The reactions of SnPh3<(CH2)nSC6H4Me-p> (n= 3 or 4) with mercury(II) chloride, bromine and iodine lead to phenyl-tin bond cleavage.In contrast, reactions with methyl iodide provide SnPh3<(CH2)nI> and MeSC6H4Me-p.Charge-transfer adducts are formed between SnPh3<(CH2)nSC6H4Me-p> (n= 1-4) and tetracyanoethylene or p-bromoanil.The values of λ_max. of the complexes indicate similar donor character for SnPh3<(CH2)nSC6H4Me-p> (n= 2,3, or 4); however, the compound SnPh3(CH2SC6H4Me-p) is a stronger donor.

Full text of DOI:10.1039/DT9820002321

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