Sulphur-substituted Organotin Compounds. Part 8. Preparation and Reactions of 3-(p-Tolylthio)propyl- and 4-(p-Tolylthio)butyl-triphenyltin. Interactions with Tetracyanoethylene

DOI: 10.1039/DT9820002321

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2321 - 2326 (1982)

Update date:2022-08-04

Topics:

Authors:

Wardell, James L.

Wigzell, John McM.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9820002321

The reactions of SnPh3<(CH2)nSC6H4Me-p> (n= 3 or 4) with mercury(II) chloride, bromine and iodine lead to phenyl-tin bond cleavage.In contrast, reactions with methyl iodide provide SnPh3<(CH2)nI> and MeSC6H4Me-p.Charge-transfer adducts are formed between SnPh3<(CH2)nSC6H4Me-p> (n= 1-4) and tetracyanoethylene or p-bromoanil.The values of λ_max. of the complexes indicate similar donor character for SnPh3<(CH2)nSC6H4Me-p> (n= 2,3, or 4); however, the compound SnPh3(CH2SC6H4Me-p) is a stronger donor.

Full text of DOI:10.1039/DT9820002321

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(C₆H₅)3SnCH₂CH₂CH₂CH₂SC₆H₄CH₃

Cas No:77329-30-7

R&D Labs maybe for 77329-30-7

Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Suzhou Zhonghelong Chemical Tech Co., Ltd【License cancellation】

Contact:+86 571-12345678

Address:Dunhuang Road, Suzhou Industrial Park, No.128 building 701 room Mansion
Wuxi Highness Chemical Co.,Ltd

website:https://www.phtpharmatech.com/

Contact:86-510-81771080

Address:No58 East Xinguan Rd, Guanlin Town, Yixing City, Jiangsu China
Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District

Relevant to this article

Ru₃(CO)₁₂-catalyzed coupling reaction of sp³ C - H bonds adjacent to a nitrogen atom in alkylamines with alkenes

Doi:10.1021/ja011540e
(2001)
A NEW CHIRAL CATALYST FOR THE ENANTIOSELECTIVE SYNTHESIS OF SECONDARY ALCOHOLS AND DEUTERATED PRIMARY ALCOHOLS BY CARBONYL REDUCTION

Doi:10.1016/S0040-4039(01)93871-7
(1989)
Pd-Catalyzed borylative polycyclization of enediynes to alkylboronates

Doi:10.1002/chem.201001124
(2011)
Studies on pyrazolo[3,4-d]pyrimidine derivatives. XVII. Reactions of 5-benzoyl-4,5-dihydro-6-methyl-1-phenyl-1H-pyrazolo[3,4-d]pyrimidine-4- carbonitrile (The 6-methylpyrazolopyrimidine Reissert compound)

Doi:10.1248/cpb.38.230
(1990)
Synthesis and properties of conjugated oligoyne-centered π-extended tetrathiafulvalene analogues and related macromolecular systems

Doi:10.1021/jo2000447
(2011)
Group 4 dimethylsilylenebisamido complexes bearing the 6-[2-(diethylboryl) phenyl]pyrid-2-yl motif: Synthesis and use in tandem ring-opening metathesis/vinyl-insertion copolymerization of cyclic olefins with ethylene

Doi:10.1002/chem.201101829
(2011)

Article Doi