PHOTOCHEMICAL REACTION OF EPOXYNAPHTHOQUINONES WITH ALCOHOLS. AN IONIC TRAPPING OF CARBONYL YLIDES

DOI: 10.1246/cl.1981.201

Source and publish data:

Chemistry Letters p. 201 - 204 (1981)

Update date:2022-08-04

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Authors:

Osuka, Atsuhiro

Suzuki, Hitomi

Maruyama, Kazuhiro

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Article abstract of DOI:10.1246/cl.1981.201

Irradiation of several 2,3-dialkyl-2,3-epoxy-2,3-dihydro-1,4-naphthoquinones in the presence of alcohol gave ring-contracted alcohol-adducts via nucleophilic addition of alcohol to carbonyl ylides.

Full text of DOI:10.1246/cl.1981.201

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