Journal of the Chemical Society. Perkin transactions I p. 24 - 28 (1981)
Update date:2022-08-04
Topics:
Hanson, James R.
Knights, Steve G.
Treatment of 17β-acetoxy-methyleneandrost-4-en-3-one under the conditions of the dienone-phenol rearrangement affords 17β-acetoxy-1α-bromomethylandrost-4-en-3-one rather than a phenol.The corresponding 3α-alcohol gave a 1α-bromothexyl-3,5-diene rather than an aromatic compounds. 2α,3α-methyleneandrost-5-ene-4,17-dione also gave a 2α-bromomethylandrost-5-ene-4,17-dione rather than a phenol.
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Doi:10.1021/jo00330a019
(1981)Doi:10.1016/S0040-4039(00)71128-2
(1980)Doi:10.1016/S0040-4039(00)71114-2
(1980)Doi:10.1007/BF00903662
(1980)Doi:10.1055/s-1981-29323
(1981)Doi:10.1007/s11095-012-0666-z
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