PHOTOSENSITIZED OXYGENATION OF PHENYLPYRUVIC ACID DERIVATIVES AS A MODEL FOR p-HYDROXYPHENYLPYRUVATE DIOXYGENASE

DOI: 10.1016/0040-4039(81)80128-1

Source and publish data:

Tetrahedron Letters p. 469 - 472 (1981)

Update date:2022-08-03

Topics:

Authors:

Kotsuki, Hiyoshizo

Saito, Isao

Matsuura, Teruo

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Article abstract of DOI:10.1016/0040-4039(81)80128-1

Dye-sensitized photooxygenation of enol ethers of methyl phenylpyruvates (3) produced diendoperoxides 4 in aprotic solvents, whereas in methanol hydroxylated product 6 was obtained.The reaction scheme is discussed in comparison with that for the enzymic transformation.

Full text of DOI:10.1016/0040-4039(81)80128-1

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