DIE BILDUNG VON ANELLIERTEN UND UEBERBRUECKTEN PRODUKTEN BEI DER INTRAMOLEKULAREN CYCLOADDITION VON CARBONYL-YLIDEN SYNTHESE EINES "INSIDE-OUTSIDE"-BICYCLOOCTADEKANS

DOI: 10.1016/S0040-4039(00)71152-X

Source and publish data:

Tetrahedron Letters p. 4909 - 4912 (1980)

Update date:2022-08-03

Topics:

Authors:

Brokatzky, Juergen

Eberbach, Wolfgang

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Article abstract of DOI:10.1016/S0040-4039(00)71152-X

Intramolecular cycloaddition reactions of carbonyl ylides with ester-activated C=C-bonds are studied.Whereas the annelated adducts 7/8 are formed in the case of 4a-c (n=1, 3, 5) as starting materials, thermolysis of 4d (n=10) leads predominantly to the bridged compound 9d.

Full text of DOI:10.1016/S0040-4039(00)71152-X

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