Journal of the American Chemical Society p. 3460 - 3467 (1981)
Update date:2022-09-26
Topics:
Danishefsky, Samuel
Zamboni, Robert
Kahn, Michael
Etheredge, Sarah Jane
The total synthesis of the title compounds are described.The starting materials were the enedione 6 and the siloxy diene 27.Cycloaddition of these compounds afforded 28, which was converted to 30.Degradation of enone 30 gave methyl ketone 32, which upon c
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