Intramolecular Diyl Trapping. Total Synthesis of dl-Hirsutene

DOI: 10.1021/ja00400a043

Source and publish data:

Journal of the American Chemical Society p. 2744 - 2749 (1981)

Update date:2022-08-04

Topics:

Authors:

Little, R. Daniel

Muller, George W.

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Article abstract of DOI:10.1021/ja00400a043

A total synthesis of the mold metabolite dl-hirsutene (4) has been achieved.The key step of the sequence utilizes a regiospecific and highly stereoselective intramolecular diyl trapping reaction to construct the requisite linearly fused tricyclopentanoid ring system (see 12 -> 18).

Full text of DOI:10.1021/ja00400a043

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