Journal of the American Chemical Society p. 2744 - 2749 (1981)
Update date:2022-08-04
Topics:
Little, R. Daniel
Muller, George W.
A total synthesis of the mold metabolite dl-hirsutene (4) has been achieved.The key step of the sequence utilizes a regiospecific and highly stereoselective intramolecular diyl trapping reaction to construct the requisite linearly fused tricyclopentanoid ring system (see 12 -> 18).
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Doi:10.1021/ja00395a022
(1981)Doi:10.1021/acs.jmedchem.7b01176
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