
Zeitschrift fur Naturforschung, B: Chemical Sciences p. 547 - 553 (2004)
Update date:2022-08-05
Topics:
Klap?tke, Thomas M.
Krumm, Burkhard
Mayer, Peter
Pentafluorobenzeneselenenyl chloride, C6F5SeCl, was reacted with various nitrogen and chalcogen substituted trimethylsilyl nucleophiles. The products, C6F5SeSCN, C6F 5SeNSO, (C6F5Se)2NMe, C 6F5SeN(Me)SiMe3, (C6F 5Se)2S and (C6F5Se)2Se, were characterized by spectroscopic methods. The reaction of C6F 5SeLi with Me3XHal compounds gave the products C 6F5SeXMe3 (X = Si, Ge, Sn, Pb). The molecular structure of (C6F5Se)2S has been determined by X-ray diffraction.
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(2004)