REACTION OF METHYL 2-DEOXY-3-O-SULFONYL-2-p-TOLUENESULFONAMIDO-α- AND β-D-GLUCOPYRANOSIDE DERIVATIVES WITH HALIDE IONS

DOI: 10.1016/S0008-6215(00)85251-9

Source and publish data:

Carbohydrate Research p. 255 - 270 (1981)

Update date:2022-08-05

Topics: Derivatives Sulfonyl Reaction Experimental Glucopyranoside

Authors:

Miyake, Toshiaki

Tsuchiya, Tsutomu

Takahashi, Yoshiaki

Umezawa, Sumio

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Article abstract of DOI:10.1016/S0008-6215(00)85251-9

Methyl 2-deoxy-3-O-sulfonyl-2-p-toluenesulfonamido-α-D-glucopyranoside derivatives were treated with halides in N,N-dimethylformamide.The corresponding 3-halo-α-D-glucopyranosides were formed by a double SN2 process in high yields via the 3-halo-α-D-allop

Full text of DOI:10.1016/S0008-6215(00)85251-9

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