HIGHLY ENANTIOSELECTIVE MICHAEL ADDITION OF THIOLS TO 2-CYCLOHEXENONE BY USING (2S,4S)-2-(ANILINOMETHYL)-1-ETHYL-4-HYDROXYPYRROLIDINE AS A CHIRAL CATALYST

DOI: 10.1246/cl.1981.165

Source and publish data:

Chemistry Letters p. 165 - 168 (1981)

Update date:2022-08-05

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Authors:

Mukaiyama, Teruaki

Ikegawa, Akihiko

Suzuki, Keisuke

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Article abstract of DOI:10.1246/cl.1981.165

Optically active 3-arylthiocyclohexanones are produced in good optical yields by treating 2-cyclohexenone with aryl thiols in the presence of (2S,4S)-2-(anilinomethyl)-1-ethyl-4-hydroxypyrrolidine as a chiral catalyst.

Full text of DOI:10.1246/cl.1981.165

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