SYNTHESIS OF PALLESCENSIN-E : USE OF CROWN ETHER IN THE WADSWORTH PROCEDURE FOR OLEFIN FORMATION

DOI: 10.1016/0040-4039(81)80176-1

Source and publish data:

Tetrahedron Letters p. 161 - 162 (1981)

Update date:2022-08-05

Topics:

Authors:

Baker, R.

Sims, R. J.

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Article abstract of DOI:10.1016/0040-4039(81)80176-1

The furanosesquiterpene, pallescensin-E has been prepared by a route involving reaction of a dimethyl 3-furylmethyl phosphonate anion with 2,3-dimethylbenzaldehyde in the presence of 15-crown-5; this reaction has been shown to have general applicability.

Full text of DOI:10.1016/0040-4039(81)80176-1

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