2-SUBSTITUTED FORTIMICINS BY RING OPENING OF 2-DEOXY-1,2-EPIMINO-2-EPI-FORTIMICIN B AND BY NUCLEOPHILIC DISPLACEMENTS OF 2-O-(METHYLSULFONYL)FORTIMICIN DERIVATIVES

DOI: 10.1016/S0008-6215(00)81869-8

Source and publish data:

Carbohydrate Research p. 185 - 204 (1981)

Update date:2022-09-26

Topics: Ring Opening Nucleophilic Displacements

Authors:

Tadanier, Jack

Martin, Jerry R.

Nadzan, Alex M.

Johnson, Paulette

Holms, James

et al. et al.

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Article abstract of DOI:10.1016/S0008-6215(00)81869-8

Opening of the aziridine ring of 2-deoxy-1,2-epimino-2-epi-fortimicin B (10) has been effected with both chloride and azide.The reactions are both stereo- and regiospecific and give 2-chloro-2-deoxyfortimicin B (2c) and 2-azido-2-deoxyfortimicin B (2d).Th

Full text of DOI:10.1016/S0008-6215(00)81869-8

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