Chemistry Letters p. 457 - 460 (1981)
Update date:2022-09-26
Topics: Synthetic studies Intermediates Optically active D-mannose Maytansinoids
Isobe, Minoru
Ichikawa, Yoshiyasu
Kitamura, Masato
Goto, Toshio
Optically active intermediates (15 and 23) for maytansine were synthesized from D-mannose via heteroconjugate addition of methyllithium as a crucial step.
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Doi:10.1021/jm00319a016
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