SIGMATROPIC 1.5-HYDROGEN SHIFT AND CONCOMITANT CYCLOPROPANE BOND CLEAVAGE ON THERMOLYSIS OF trans-1-ISOPROPENYL-4-METHYLENE spiroALKANES INTO 1-METHYLENE-(3'-METHYLBUT-2'-ENYL)-CYCLOALK-2-ENES

DOI: 10.1016/S0040-4039(01)92525-0

Source and publish data:

Tetrahedron Letters p. 691 - 694 (1981)

Update date:2022-08-05

Topics:

Authors:

Sarel, Shalom

Schlossman, Ada

Langbeheim, Marcel

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)92525-0

Thermolysis of several trans-1-isopropenyl-4-methylene-spiro<2.x>-alkanes (x=4,5) in xylene solution at 130 deg C causes quantitative rearrangement to 1-methylene-2-(3'-methylbut-2'-enyl)cycloalkanes (3-4).

Full text of DOI:10.1016/S0040-4039(01)92525-0

Products guided by the article

Product name:1-methylene-2-(3'-methylbut-2'-enyl)-cyclohex-2-ene

Cas No:78074-25-6

R&D Labs maybe for 78074-25-6

Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Jai Radhe Sales

website:http://www.jairadhesales.com

Contact:0091-79-26431096

Address:309 Harikrupa Tower,Nr old Sharda Mandir Char Rasta,Ellisbridge
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512

Relevant to this article

Cobalt(II)-Catalyzed Bisfunctionalization of Alkenes with Diarylphosphine Oxide and Peroxide

Doi:10.1002/adsc.201900873
(2019)
Antiinflammatory 5,6-Dihydro-11-oxodibenzazepine-3-acetic Acids

Doi:10.1021/jm00141a018
(1981)
Leishmania UDP-sugar pyrophosphorylase: The missing link in galactose salvage?

Doi:10.1074/jbc.M109.067223
(2010)
New Synthetic Route for the Preparation of 4-Phenylthio-4-butanolide Derivatives by the Use of the Pummerer Rearrangement

Doi:10.1246/bcsj.54.817
(1981)
4-t-Butylperoxypyrimidine, 2,4-Di-t-butylperoxy- und 4,6-Di-t-butylperoxypyrimidine

Doi:10.1055/s-1981-29468
(1981)
Nonclassical Heteropentalenes Containing the Selenodiazole, Thiatriazole, and Selenotriazole Ring Systems

Doi:10.1021/jo00333a027
(1981)

Article Doi