INSERTION REACTIONS OF ELECTRON-DEFICIENT SPECIES: INSERTION OF GERMYLENES AND PHENYLPHOSPHINIDENE INTO GERMANIUM-GERMANIUM BONDS

DOI: 10.1016/S0022-328X(00)86642-5

Source and publish data:

Journal of Organometallic Chemistry p. 37 - 42 (1981)

Update date:2022-08-05

Topics:

Authors:

Castel, A.

Escudie, J.

Riviere, P.

Satge, J.

Bochkarev, M.N.

Et Al. Et Al.

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Article abstract of DOI:10.1016/S0022-328X(00)86642-5

The reactions of germylenes with pentafluorophenyl- and alkylpentafluorophenyl-digermanes give the trigermanes (X=F, Cl; Y=F, Ph; R=C6F5, Et).Their thermal decomposition involves α-elimination to give halogermanes and germylgermylenes.These last

Full text of DOI:10.1016/S0022-328X(00)86642-5

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