Thermal Rearrangement of 1-(3-Methylbut-2-enyloxy)-4-prop-1-enylbenzene (Feniculin): a New Synthesis of Anisoxide and Re-investigation of the Consituents of Star Anise Oil

DOI: 10.1039/P19810000897

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 897 - 899 (1981)

Update date:2022-08-05

Topics:

Authors:

Okely, Martyn H.

Grundon, Michael F.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810000897

At 153 deg C feniculin (1) undergoes Claisen rearrangement to the 1,1-dimethylallylphenol (3), which is slowly converted into the 1,2-dimethylallylphenol (4); the products of the abnormal Claisen rearrangement, phenol (4) and anisoxide (2), are formed at

Full text of DOI:10.1039/P19810000897

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:5-prop-1-enyl-2,3,3-trimethyl-2,3-dihydrobenzofuran

Cas No:78259-73-1

R&D Labs maybe for 78259-73-1

Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
Neostar United Industrial Co., Ltd.

Contact:0519-85557386

Address:Yangtze River North Road, Binjiang Economic Development Zone
Jiaozuo Zhongwen Trading Coporation Limited

Contact:--

Address:East Renmin Road
Shijiazhuang Haitian Amino Acid Co., Ltd.

Contact:+86-311-88908111

Address:Shijiazhuang Hebei province,China
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road

Relevant to this article

New Synthetic Route for the Preparation of 4-Phenylthio-4-butanolide Derivatives by the Use of the Pummerer Rearrangement

Doi:10.1246/bcsj.54.817
(1981)
4-t-Butylperoxypyrimidine, 2,4-Di-t-butylperoxy- und 4,6-Di-t-butylperoxypyrimidine

Doi:10.1055/s-1981-29468
(1981)
Nonclassical Heteropentalenes Containing the Selenodiazole, Thiatriazole, and Selenotriazole Ring Systems

Doi:10.1021/jo00333a027
(1981)
Dynamic kinetic asymmetric transformations of β-stereogenic α-ketoesters by direct aldolization

Doi:10.1002/anie.201306873
(2014)
Synthesis of Some Substituted Difluoronitroacetanilides and Their Reduction to Substituted N-Difluoronitroethylanilines

Doi:10.1016/S0022-1139(00)82254-X
(1981)
Transition-State Barrier for Electrophilic Reactions. Solvation of Charge-Transfer Ion Pair as the Unifying Factor in Alkene Addition and Aromatic Substitution with Bromine

Doi:10.1021/ja00390a035
(1982)

Article Doi