Thermal Rearrangement of 1-(3-Methylbut-2-enyloxy)-4-prop-1-enylbenzene (Feniculin): a New Synthesis of Anisoxide and Re-investigation of the Consituents of Star Anise Oil

DOI: 10.1039/P19810000897

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 897 - 899 (1981)

Update date:2022-08-05

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Authors:

Okely, Martyn H.

Grundon, Michael F.

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Article abstract of DOI:10.1039/P19810000897

At 153 deg C feniculin (1) undergoes Claisen rearrangement to the 1,1-dimethylallylphenol (3), which is slowly converted into the 1,2-dimethylallylphenol (4); the products of the abnormal Claisen rearrangement, phenol (4) and anisoxide (2), are formed at

Full text of DOI:10.1039/P19810000897

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