
Tetrahedron Letters p. 895 - 898 (1981)
Update date:2022-08-03
Topics: Synthesis Characterization NMR spectroscopy X-ray crystallography
Miller, Bernard
Marhevka, Virginia Creedon
Secondary alcohols in the 9,10-dihydro-9-anthrol series frequently undergo acid-catalyzed elimination and substitution reactions more rapidly than do corresponding tertiary alcohols - a phenomenon attributed to predominant existence of the tertiary alcohols in triptycene-like conformations with the hydroxy groups in pseudoequatorial positions.
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Doi:10.1016/0040-4039(81)89021-1
(1981)Doi:10.1021/ol202452b
(2011)Doi:10.1007/BF00505995
(1981)Doi:10.1021/ic50225a045
(1981)Doi:10.1021/acs.joc.0c00792
(2020)Doi:10.1080/00268948108074677
(1981)