DIALKYLATION AND METHOXYALKYLATION OF BUTADIENE WITH DIETHYL MALONATE ANIONS

DOI: 10.1016/S0040-4039(01)82864-1

Source and publish data:

Tetrahedron Letters p. 1055 - 1058 (1981)

Update date:2022-09-26

Topics:

Authors:

Akermark, Bjoern

Ljungqvist, Anders

Panunzio, Mauro

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Article abstract of DOI:10.1016/S0040-4039(01)82864-1

Butadiene has been transformed into diethyl 2,7-diethoxycarbonyl-4-octenedioates and ethyl 2-ethoxycarbonyl-6-methoxy-4-hexenoates by reacting ?-4-chloro- and 4-methoxybutenylpalladium complexes, respectively, with malonate anions.

Full text of DOI:10.1016/S0040-4039(01)82864-1

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