NOVEL CONVERSION OF A KETONE DIMETHYL DITHIOACETAL S,S-DIOXIDE TO THE CORRESPONDING KETONE AND ITS APPLICATION TO SYNTHESIS OF ACYCLIC AND CYCLIC KETONES

DOI: 10.1246/cl.1982.813

Source and publish data:

Chemistry Letters p. 813 - 814 (1982)

Update date:2022-08-03

Topics:

Authors:

Ogura, Katsuyuki

Suzuki, Michiyo

Watanabe, Jun-ichi

Yamashita, Mitsuo

Iida, Hirotada

Tsuchihashi, Gen-ichi

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Article abstract of DOI:10.1246/cl.1982.813

A ketone dimethyl dithioacetal S,S-dioxide was easily hydrolyzed with hydrochloric acid in refluxing methanol and this transformation was applied to a new method for making acyclic and cyclic ketones by the use of formaldehyde dimethyl dithioacetal S,S-dioxide.

Full text of DOI:10.1246/cl.1982.813

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