REACTIONS OF A (η3-VINYLCARBENE)IRON COMPLEX WITH DIAZO COMPOUNDS: FORMATION OF (η4-BUTADIENE)IRON DERIVATIVES

DOI: 10.1016/S0022-328X(00)85960-4

Source and publish data:

Journal of Organometallic Chemistry p. 87 - 92 (1981)

Update date:2022-08-03

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Authors:

Mitsudo, Take-Aki

Watanabe, Hiroyoshi

Watanabe, Katsuya

Watanabe, Yoshihisa

Takegami, Yoshinobu

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Article abstract of DOI:10.1016/S0022-328X(00)85960-4

A (η³-vinylcarbene)tricarbonyliron complex I reacted with diazo compounds affording (η⁴-butadiene)tricarbonyliron complexes (Va-Vc) by the insertion of the methylene group of the diazo compounds into the carbene carbon-iron bond .

Full text of DOI:10.1016/S0022-328X(00)85960-4

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