Journal of Organometallic Chemistry p. 341 - 354 (1981)
Update date:2022-08-05
Topics:
Dormond, A.
Duval-Huet, C.
Tirouflet, J.
The synthesis of η5-Cp'3UCl, η5-Cp-η5-Cp'2UCl, η5-Cp2-η5-Cp'UCl (Cp = C5H5; Cp' = substituted cyclopentadienyl) complexes and of similar complexes bridged between the two cyclopentadienyl ligands is described.Several complexes of this type have a prochiral uranium atom.The bridged complexes obtained from the bidentate dianion a chiral carbon and a chiral uranium atom in the same structure.The two diastereoisomeric forms have not been separated but are easily identified by NMR analysis.
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Doi:10.1002/jps.2600671235
(1978)Doi:10.1016/S0022-328X(00)81912-9
(1981)Doi:10.1021/ja00410a020
(1981)Doi:10.1021/jm00143a008
(1981)Doi:10.1016/j.jcat.2013.02.020
(2013)Doi:10.1016/S0040-4020(01)92055-1
(1981)
