COMPLEXES CYCLOPENTADIENYLES DE L'URANIUM(IV). II. COMPLEXES TRICYCLOPENTADIENYLES D'URANIUM(IV) A CHIRALITE CENTRO-METALLEE. DIASTEREOTOPIE ET DIASTEREOISOMERIE

DOI: 10.1016/S0022-328X(00)81191-2

Source and publish data:

Journal of Organometallic Chemistry p. 341 - 354 (1981)

Update date:2022-08-05

Topics:

Authors:

Dormond, A.

Duval-Huet, C.

Tirouflet, J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)81191-2

The synthesis of η⁵-Cp'3UCl, η⁵-Cp-η⁵-Cp'2UCl, η⁵-Cp2-η⁵-Cp'UCl (Cp = C5H5; Cp' = substituted cyclopentadienyl) complexes and of similar complexes bridged between the two cyclopentadienyl ligands is described.Several complexes of this type have a prochiral uranium atom.The bridged complexes obtained from the bidentate dianion ^2- bear a chiral carbon and a chiral uranium atom in the same structure.The two diastereoisomeric forms have not been separated but are easily identified by NMR analysis.

Full text of DOI:10.1016/S0022-328X(00)81191-2

Products guided by the article

Product name:(C₅H₅)2(C₅H₄CH(CH₃)C₆H₅)UCl

Cas No:78790-03-1

R&D Labs maybe for 78790-03-1

Hangzhou Haiqiang Chemical Co.,Ltd.

Contact:+86-571-86960370

Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Hefei Highzone Fine Chemical S&T CO.,LTD

Contact:86-0551-63663560

Address:room 1801 NO. 24 Shuguang RD.
Zhengzhou Xinlian Chemical Tech Co. ,Ltd

Contact:0371-65771781 021-52042910

Address:H Part, Building I, No. 700 Gonglu Road, Pudong New Area, Shanghai
HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
Guangzhou Puho Pharmaceutical Technology Co. Ltd.

Contact:86-20-29848035/29848075

Address:No.166, Chaoyang East Road, Panyu District, Guangzhou City, Guangdong Province

Relevant to this article

Doi:10.1002/jps.2600671235
(1978)
ORGANOTIN HYDRIDE ADDITIONS TO E- AND Z-TRISUBSTITUTED ETHYLENES.SYNTHESIS OF SOME NEW FUNCTIONALLY SUBSTITUTED ORGANOTIN COMPOUNDS

Doi:10.1016/S0022-328X(00)81912-9
(1981)
Highly Reduced Organometallics. 5. Synthesis, Properties, and the Molecular Structure of (Ph3PAu)3V(CO)5, A Gold-Vanadium Cluster

Doi:10.1021/ja00410a020
(1981)
Acidic epinephrine analogues derived from 1H,3H-2,1,3-benzothiadiazole 2,2-dioxide and from trifluoromethanesulfonanilide. A new synthesis of 1H,3H-2,1,3-benzothiadiazole 2,2-dioxide

Doi:10.1021/jm00143a008
(1981)
Characterization of sites of different thermodynamic affinities on the same metal center via isothermal titration calorimetry

Doi:10.1016/j.jcat.2013.02.020
(2013)
α-SUBSTITUIERTE PHOSPHONATE-36 α-PHOSPHONOENAMINE UND ACYLPHOSPHONATE DURCH HORNER-OLEFINIERUNG

Doi:10.1016/S0040-4020(01)92055-1
(1981)

Article Doi