STANNANES IN SYNTHESIS: A NEW ROUTE TO 2-SUBSTITUTED-1,3-BUTADIENES VIA STEREOSELECTIVE ALLYLTIN FORMATION UNDER HOMOLYTIC CONDITIONS

DOI: 10.1016/S0040-4039(01)92967-3

Source and publish data:

Tetrahedron Letters p. 2675 - 2678 (1981)

Update date:2022-09-26

Topics:

Authors:

Ueno, Yoshio

Sano, Hiroshi

Aoki, Seiichi

Okawara, Makoto

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Article abstract of DOI:10.1016/S0040-4039(01)92967-3

α-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile (AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substitued-1,3-butadienes upon distillation in good yield.

Full text of DOI:10.1016/S0040-4039(01)92967-3

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