STANNANES IN SYNTHESIS: A NEW ROUTE TO 2-SUBSTITUTED-1,3-BUTADIENES VIA STEREOSELECTIVE ALLYLTIN FORMATION UNDER HOMOLYTIC CONDITIONS

DOI: 10.1016/S0040-4039(01)92967-3

Source and publish data:

Tetrahedron Letters p. 2675 - 2678 (1981)

Update date:2022-09-26

Topics:

Authors:

Ueno, Yoshio

Sano, Hiroshi

Aoki, Seiichi

Okawara, Makoto

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)92967-3

α-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile (AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substitued-1,3-butadienes upon distillation in good yield.

Full text of DOI:10.1016/S0040-4039(01)92967-3

Products guided by the article

Product name:6-Methyl-2-(toluene-4-sulfonyl)-2-vinyl-hept-5-en-1-ol

Cas No:79240-18-9

R&D Labs maybe for 79240-18-9

SOGA ENTERPRISES ASIA GROUP

Contact:+86-633-8332928

Address:No.1,Huanghai Yilu.Rizhao,Shandong
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Chemsigma International Co.,Ltd.

website:http://www.chemsigma.com

Contact:86-025-58748998

Address:Rm.705, 15th Building,Rd.Xinke II
HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
Aqua Chem Industry Co., Ltd

Contact:+86-515-88356562

Address:No.2, West Daqing Road, Yancheng, Jiangsu, China

Relevant to this article

Design and synthesis of 5′-deoxy-5′-phenyladenophostin A, a highly potent IP₃ receptor ligand

Doi:10.1021/ol0602710
(2006)
Substituted Imidazo<1,2-a>pyridine-2-carbamate Anthelmintics

Doi:10.1021/jm00144a030
(1981)
FeBr₃-catalyzed dibromination of alkenes and alkynes

Doi:10.1016/j.cclet.2011.05.005
(2011)
Novel Generation of Phenylsulfenium Ion and Aromatic Phenylthiolation. Reactions of Hydrazoic Acid, Alkyl Azides and Hydroxylamine Derivatives with Alkyl Phenyl Sulfides in the Presence of Both Trifluoromethanesulfonic Acid and Trifluoroacetic Acid

Doi:10.1039/c39920000916
(1992)
Asymmetric chemoenzymatic synthesis of miconazole and econazole enantiomers. the importance of chirality in their biological evaluation

Doi:10.1021/jo102459w
(2011)
Bioactive pseudo-C-nucleosides containing thiazole, thiazolidinone, and tetrazole rings

Doi:10.1081/CAR-200060396
(2005)

Article Doi