Catalytic Mechanisms of Acyl Transfer Reactions in Dipolar Aprotic Media. 2. Electrophilic Activation of the Carbonyl Group by Quaternary Alkylammonium and Imidazolium Functions

DOI: 10.1021/ja00410a035

Source and publish data:

Journal of the American Chemical Society p. 6192 - 6197 (1981)

Update date:2022-08-04

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Authors:

Hajdu, Joseph

Smith, Georgianna M.

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Article abstract of DOI:10.1021/ja00410a035

Crown ether solvated potassium acetate in dipolar aprotic media readily converts p-nitrophenyl o-toluate to the corresponding acetyltoluyl mixed anhydride.The reaction proceeds at room temperature in quantitative yield.The rate of acyl transfer is 0.0118

Full text of DOI:10.1021/ja00410a035

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