Monatshefte fur Chemie p. 617 - 626 (1981)
Update date:2022-08-03
Topics:
Allen, Anthony A.
Kurzer, Frederick
The interaction of 1-chlorodi-isophor-2(7)-en-3-one or its 5,11-bisnor-homologue with potassium phthalimide yields the corresponding 1-phthalimido-compounds, which are converted into the 1-amines on treatment with hydrazine, followed by hydrolysis. 1-Aminodi-isophor-2(7)-ene is not accessible by this route, but its N-acyl-derivatives are obtainable directly from 1-hydroxydi-isophor-2(7)-ene by the Ritter reaction; the 3-keto-analogue reacts similarly.Some properties of the novel 1-aminodi-isophoranes are described. - Keywords: Di-isophorones, 1-amino; Tricyclo<7.3.1.02,7>tridecanes
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Doi:10.1016/S0040-4039(01)00845-0
(2001)Doi:10.1007/BF00899786
(1981)Doi:10.1016/S1381-1169(02)00331-X
(2002)Doi:10.1021/ol047639i
(2005)Doi:10.1246/bcsj.54.2227
(1981)Doi:10.1021/jo00341a009
(1982)
