Journal of Organic Chemistry p. 5143 - 5147 (1981)
Update date:2022-08-04
Topics:
Kwart, H.
George, T. J.
Horgan, A. G.
Lin, Y. T.
The temperature dependence of kH/kD for the formation of benzaldehyde through base-catalyzed HNO2 elimination from benzyl nitrate is indicative of a tunneling pathway of linear proton transfer.The same criterion applied to the uncatalyzed, gas-phase reaction reveals a cyclic transition state of nonlinear proton transfer.From these and other considerations it has been deduced that the base-catalyzed reaction is best formulated as a cyclic process of linear H transfer and is consistent with an ECO1cb rather than the ECO2 mechanism previously claimed.
View MoreShanghai doly chemical Co.,Ltd
Contact:+86-21-34716221
Address:No.328,WuHe Roard,MinHang,ShangHai China
Guangzhou Probig Fine Chemical Co., Ltd.
Contact:020-86297874
Address:No.2, 1/F, No.20, Hetai Road,Hebian Village, Baiyun District,Guangzhou,China
Contact:+1-284-4950244
Address:Box 3069, Road Town, Tortola, British Virgin Islands
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
Contact:+86-579-85206992
Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Doi:10.1021/jo00339a049
(1981)Doi:10.1021/jo049137o
(2004)Doi:10.1021/ma035997f
(2004)Doi:10.1016/0040-4039(96)01737-6
(1996)Doi:10.1007/BF00905076
(1981)Doi:10.1081/NCN-200060036
(2005)
